Product ID:OCE F3 TONER, E-182-C-US
MSDS Date:08/01/1997
FSC:NIIN:Submitter:N EN
Status Code:A
MSDS Number: CKSVH

OCE-USA, INC

5450 NORTH CUMBERLAND AVENUE
CHICAGO, IL 60658
US

Emergency Phone: (800) 424-9300

Info Phone: 773-714-8500

Cage: 08MJ9

OCE-USA, INC

CHICAGO, IL 60658 US

Telephone: 773-714-8500

Cage: 08MJ9

POLYESTER RESIN. (MFR CAS #170831-75-1)

IRON OXIDE

CAS: 1317-61-9

PHENOXY RESIN (MFR CAS NO. PMN P-95-461)

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

AMORPHOUS SILICA. (MFR CAS NO. 68611-44-9)

CAS: 112926-00-8

RTECS: VV7315000

OSHA PEL SEE TABLE Z-3

ACGIH TLV: 10 MG/M3

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:IN A TONER DUST CLOUD, FORMATION OF AN
EXPLOSIVE DUST-AIR MIXTURE IS POSSIBLE. TONER DUST MAY CAUSE
DISCOMFORT TO THE EYES AND RESPIRATORY TRACT, IN THE SAME MANNER AS
INERT NUISANCE DUST. TO OUR KNOW LEDGE, WITH DUE OBSERVANCE OF REC
EXPOSURE LIMIT & OF NORMAL HYGIENE THIS PRODUCT PRESENTS NO HEALTH
HAZARD IN NORMAL USE. INHALATION: AT HIGH CONCENTRATION IN THE AIR
POWDER MAY CAUSE DISCOMFORT OF U PPER RESPIRATORY SYSTEM. SKIN: NO
ADVERSE HEALTH EFFECTS ARE EXPECTED. EYES: DUST MAY CAUSE
DISCOMFORT IN SAME MANNER AS NUISANCE DUST. INGESTION: CONSIDERED
RELATIVELY HARMLESS.

First Aid:EYES: RINSE WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
SKIN: WASH WITH COLD WATER & SOAP. INHALATION: CLEAN NOSE, MOUTH,
THROAT. COUGH UP. FRESH AIR. INGESTION: RINSE MOUTH WITH WATER. IF
LARGE QU ANTITY SWALLOWED, SEEK MEDICAL ADVICE. FOR ANY MEDICAL
ADVICE, TAKE ALONG THIS MATERIAL SAFETY DATA SHEET.

Flash Point:N.A (=NOT APPLI)
Autoignition Temp:=500.C, 932.F
Autoignition Temp Text:APPROX
Lower Limits:60 G/M3
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY (FOG),
FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .

Spill Release Procedures:SPILLS CAN BE CLEANED WITH A VACUUM CLEANER OR
A DAMP RAG. DO NOT USE WARM WATER BECAUSE THIS MAKES THE TONER SOFT
AND STICKY.

Handling and Storage Precautions:KEEP BOTTLE TIGHTLY CLOSED TO PREVENT
DUST FORMATION. HANDLE CAREFULLY. AVOID BREATHING DUST. NO SPECIAL
TECHNICAL MEASURES FOR STORAGE.

Respiratory Protection:A NIOSH APPROVED RESPIRATOR APPROPRIATE FOR THE
EXPOSURE OF CONCERN .
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED SAFETY GLASSES .
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . NO SPECIAL TECHNICAL MEASURES. NO PERSONAL
PROTECTIVE EQUIPMENT NEEDED (MFR).
Work Hygienic Practices:AFTER SKIN CONTACT, WASH WITH COLD WATER AND
SOAP.
Supplemental Safety and Health
THRESHOLD LIMIT VALUE FOR: NUISANCE DUST: 10 MG/M3; CARBON BLACK: 3.5
MG/M3; AMORPHOUS SILICA: 10 MG/M3.

Boiling Pt:B.P. Text:N.A
Vapor Pres:N.A
Vapor Density:N.A
pH:N.A
Evaporation Rate & Reference:N.A
Solubility in Water:INSOLUBLE
Appearance and Odor:BLACK POWDER, FAINT ODOR.
Percent Volatiles by Volume:0%

Stability Indicator/Materials to Avoid:YES
HAZARDOUS REACTION: NONE.
Stability Condition to Avoid:COMBUSTION PRODUCTS: CARBON DIOXIDE,
CARBON MONOXIDE, WATER.
Hazardous Decomposition Products:NONE AT INTENDED USE. THERMAL
DECOMPOSITION: ABOVE APPROX. 450 C (842 F).

Waste Disposal Methods:MATERIAL IS NOT CLASSIFIED AS HAZARDOUS WASTE
UNDER THE PRESENT EPA REGULATIONS. PACK WASTE DUSTPROOF TO PREVENT
DUSTING. WITH DUE OBSERVANCE OF LOCAL LAWS & REGS, DISPOSE OF BY
BURIAL IN SANITARY LAN DFILL OR INCINERATION. DO NOT THROW IN OPEN
FIRE IN ORDER TO PREVENT RISK OF DUST EXPLOSION.

Toxicological Information:MUTAGENICITY: NO MUTAGENICITY DETECTED IN
AMES TEST. THESE STATEMENTS ARE BASED ON TOXICOLOGICAL LITERATURE
ON INGREDIENTS OF THIS PRODUCT AND TEST RESULTS OF SIMILAR PRODUCT.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:THIS PRODUCT IS NOT BIODEGRADABLE. THE INGREDIENTS ARE NOT
CLASSIFIED AS ECOLOGICALLY HAZARDOUS. NO ADVERSE ENVIRONMENTAL
EFFECTS ARE EXPECTED. TRANSPORT: INGREDIENTS AND STATEMENT OF
MUTAGENICITY CHA NGED. INFORMATION ABOUT CARBON BLACK ADDED.
MATERIAL SAFETY DATA SHEET (93/112/EEC AND ISO 11014).

Transport Information:THIS PRODUCT IS NOT CLASSIFIED AS A DANGEROUS
SUBSTANCE ACCORDING TO THE INTERNATIONAL TRANSPORT REGULATIONS.
STATE REG: CARBON BLACK, IARC CONCLUDED THAT "THERE IS INADEQUATE
EVIDENCE IN HUMANS FOR T HE CARCINOGENICITY OF CARBON BLACK".
CHRONIC OVEREXPOSURE TO MANY DUSTS, INCLUDING CARBON BLACK DUST,
MAY RESULT IN RESPIRATORY TRACT IRRITATION AND SLIGHT CHANGES IN
LUNG FUNCTION. ROOM VENTILATION: SEE OPERATOR MANUAL OR SAFETY
DATA SHEET FOR THE COPIER. USE: INK POWDER FOR COPIERS. REVISION OF
E-182-B-US DATED SEPTEMBER 1996. MODIFICATIONS:
COMPOSITION/INFORMATION ON (ECOLOGICAL)

Federal Regulatory Information:APPLICABLE REGULATION: 29 CFR PART
1910.1200 HAZARD COMMUNICATION. HAZARD AND SAFETY INFORMATION ON
THE LABEL: HANDLE CAREFULLY; AVOID BREATHING DUST.
State Regulatory Information:OTHER INFO:THAN RATS HAVE NOT DEMOSTRATED
AN ASSOCIATION BETWEEN CARBON BLACK AND LUNG TUMORS. MOREOVER, A 2
YR CANCER BIOASSAY USING A TYPICAL TONER PREPARATION CONTAINING
CARBON BLACK DEMONSTRATED N O ASSOCIATION BETWEEN TONER EXPOSURE
AND TUMOR DEVELOPMENT IN RATS. EPIDEMIOLOGY STUDIES OF WORKERS IN
CARBON BLACK PRODUCING INDUSTRIES OF NORTH AMERICA AND WESTERN
EUROPE DO NOT DEMONSTRATE AN ASSOC IATION BETWEEN CARBON BLACK AND
CANCER, EVEN IN HIGH EXPOSURE OCCUPATIONAL SETTINGS. IN ADDITION,
IN ITS RE-EVALUATION OF (TRANSPORT)